Basics of Ocean Acidification

Updates added below June 20 and 24, 2015

Update below July 2, 2015: Ocean pH is actually trending alkaline

Update below September 15, 2015: Extensive discussion of ocean chemistry

If surface temperatures don’t skyrocket soon, expect to hear a lot in the coming months about “ocean acidification.”  This sounds scary, and that is the point of emphasizing it in the runup to Paris COP.

So here’s the basic chemistry of CO2 and H20:

8lrtxibuouhqy8limppbfwkc76e5k_rxa9xbrm8mssw

That seems straight forward,  So what is the problem?

That looks fairly serious.  So what does the IPCC have to say about this issue?

What does it say in the SPM (Summary for Policy Makers)?

For this issue, I looked at the topic of ocean acidification and fish productivity. The SPM asserts on Page 17 that fish habitats and production will fall and that ocean acidification threatens marine ecosystems.

“Open-ocean net primary production is projected to redistribute and, by 2100, fall globally under all RCP scenarios. Climate change adds to the threats of over-fishing and other non-climatic stressors, thus complicating marine management regimes (high confidence).” Pg 17 SPM

“For medium- to high-emission scenarios (RCP4.5, 6.0, and 8.5), ocean acidification poses substantial risks to marine ecosystems, especially polar ecosystems and coral reefs, associated with impacts on the physiology, behavior, and population dynamics of individual species from phytoplankton to animals (medium to high confidence).” Pg 17 SPM

So, the IPCC agrees that ocean acidification is a serious problem due to rising CO2 emissions from burning fossil fuels.

What does it say in the Working Group Reports?

But wait a minute.  Let’s see what is in the working group reports that are written by scientists, not politicians.

WGII Report, Chapter 6 covers Ocean Systems. There we find a different story with more nuance and objectivity:

“Few field observations conducted in the last decade demonstrate biotic responses attributable to anthropogenic ocean acidification” pg 4

“Due to contradictory observations there is currently uncertainty about the future trends of major upwelling systems and how their drivers (enhanced productivity, acidification, and hypoxia) will shape ecosystem characteristics (low confidence).” Pg 5

“Both acclimatization and adaptation will shift sensitivity thresholds but the capacity and limits of species to acclimatize or adapt remain largely unknown” Pg 23

“Production, growth, and recruitment of most but not all non-calcifying
seaweeds also increased at CO2 levels from 700 to 900 µatm Pg 25

“Contributions of anthropogenic ocean acidification to climate-induced alterations in the field have rarely been established and are limited to observations in individual species” Pg. 27

“To date, very few ecosystem-level changes in the field have been attributed to anthropogenic or local ocean acidification.” Pg 39

Ocean Chemistry on the Record

Contrast the IPCC headlines with the the Senate Testimony of John T. Everett, in which he said:

“There is no reliable observational evidence of negative trends that can be traced definitively to lowered pH of the water. . . Papers that herald findings that show negative impacts need to be dismissed if they used acids rather than CO2 to reduce alkalinity, if they simulated CO2 values beyond triple those of today, while not reporting results at concentrations of half, present, double and triple, or as pointed out in several studies, they did not investigate adaptations over many generations.”

“In the oceans, major climate warming and cooling and pH (ocean pH about 8.1) changes are a fact of life, whether it is over a few years as in an El Niño, over decades as in the Pacific Decadal Oscillation or the North Atlantic Oscillation, or over a few hours as a burst of upwelling (pH about 7.59-7.8) appears or a storm brings acidic rainwater (pH about 4-6) into an estuary.”
http://www.epw.senate.gov/public/index.cfm?FuseAction=Files.View&FileStore_id=db302137-13f6-40cc-8968-3c9aac133b16

Many organisms benefit from less alkaline water.

(Added in thanks to David A.’s comment below)

In addition, IPCC has ignored extensive research showing positive impacts on marine life from lower pH. These studies are catalogued at CO2 Science with this summary:

There are numerous observations of improvement in calcification of disparate marine life in realistic rates of PH change due to increased CO2.

“In the final graphical representations of the information contained in our Ocean Acidification Database, we have plotted the averages of all responses to seawater acidification (produced by additions of both HCl and CO2) for all five of the life characteristics of the various marine organisms that we have analyzed over the five pH reduction ranges that we discuss in our Description of the Ocean Acidification Database Tables, which pH ranges we illustrate in the figure below.”

“The most striking feature of Figure 11 is the great preponderance of data located in positive territory, which suggests that, on the whole, marine organisms likely will not be harmed to any significant degree by the expected decline in oceanic pH. If anything, in fact, the results suggest that the world’s marine life may actually slightly benefit from the pH decline, which latter possibility is further borne out by the scatter plot of all the experimental data pertaining to all life characteristic categories over the same pH decline range, as shown below in Figure 12.”

At PH decline from control of .125, calcification, metabolism, fertility, growth and survival all moved into positive territory.

http://www.co2science.org/data/acidification/acidification.php

Summary

The oceans are buffered by extensive mineral deposits and will never become acidic. Marine life is well-adapted to the fluctuations in pH that occur all the time.

This is another example of climate fear-mongering:  It never happened before, it’s not happening now, but it surely will happen if we don’t DO SOMETHING!.

Conclusion

Many know of the Latin phrase “caveat emptor,” meaning “Let the buyer beware”.

When it comes to climate science, remember also “caveat lector”–”Let the reader beware”.

Update added June 20, 2015

For additional commentary on ocean acidification:

http://www.newsmax.com/FastFeatures/ocean-acidification-global-warming-quotes-debate/2015/05/06/id/642876/

Update added June 24, 2015

Patrick Moore also provides a thorough debunking here:

“It is a fact that people who have saltwater aquariums sometimes add CO2 to the water in order to increase coral growth and to increase plant growth. The truth is CO2 is the most important food for all life on Earth, including marine life. It is the main food for photosynthetic plankton (algae), which in turn is the food for the entire food chain in the sea.”

http://news.heartland.org/editorial/2015/05/27/why-coral-reefs-and-shellfish-will-not-die-ocean-acidification

Update added July 2, 2015

Scientists have had pH meters and measurements of the oceans for one hundred years. But experts decided that computer simulations in 2014 were better at measuring the pH in 1910 than the pH meters were. The red line (below) is the models recreation of ocean pH. The blue stars are the data points — the empirical evidence.

What we have here is one of the basic foundations of the climate change scare, that is falling ocean pH levels with increased atmospheric CO2 content, being completely dismissed by the empirical ocean pH data the alarmist climate scientists didn’t want to show anyone because it contradicted their ‘increasing ocean acidity’ narrative.

http://joannenova.com.au/2015/01/oceans-not-acidifying-scientists-hid-80-years-of-ph-data/

Update added September 15, 2015

In summary, recent research publications are using a term (OA) that is technically incorrect, misleading, and pejorative; it could not be found in the oceanography literature before about 15 years ago. . .

The claim that the surface-water of the oceans has declined in pH from 8.2 to 8.1, since the industrial revolution, is based on sparse, contradictory evidence, at least some of which is problematic computer modeling. Some areas of the oceans, not subject to algal blooms or upwelling, may be experiencing slightly lower pH values than were common before the industrial revolution. However, forecasts for ‘average’ future pH values are likely exaggerated and of debatable consequences. The effects of alkaline buffering and stabilizing biological feedback loops seem to be underappreciated by those who carelessly throw around the inaccurate term “ocean acidification.”

http://wattsupwiththat.com/2015/09/15/are-the-oceans-becoming-more-acidic/

How About That Blob? (June 13 Update)

June 13, 2015

As hoped for by Paris COP promoters, and by Californians looking for El Nino precipitation, the Blob in the North Pacific has intensified and may at least partly fulfill both expectations.

HADSST3 results for May are now in, and the sea surface temperature warming anomaly is up:

Global +0.12C over last May,
NH +0.16C over last May.

That will show up also in air temperature estimates, since 71% of the earth’s surface is covered by oceans. For example, UAH TLT anomalies show Global oceans +0.06C over last May, but Global land -0.1C, so Global UAH is only up +0.02C over May 2014. (Note: UAH uses satellites to measure air temperatures many meters above land or ocean, while surface datasets like HADCRUT, BEST, GISTEMP use the measured SSTs in their global mean temperature estimates).

The Blob difference shows up in UAH in the NH results: NH anomaly is +0.07 over last year, with the same increase showing over land and ocean.  Interestingly, UAH shows the North Pole cooler than a year ago, the TLT over the Arctic being -0.06 less than a year ago.  The South Pole land air temps are a whopping -0.2C colder than last May.

As far as Arctic Ice is concerned, the Blob probably caused the Bering Sea to melt out more than one month earlier than last year.  About 10% of the water entering the Arctic Ocean comes from Bering, so there should be some impact on ice melting the immediate BCE region (Beaufort, Chukchi, East Siberian Seas). So far, in that region, 2015 is tracking last year’s melt at a slightly lower extent -4%, not yet a significant effect from the Blob.

More on Arctic Ice melt season here:

https://rclutz.wordpress.com/2015/06/02/arctic-ice-watch-june-daily/

Background on the Blob

Many have noticed the warm water anomaly in the Northern Pacific, which shows up as a weak El Nino, but somewhat unexpected and out of the ordinary pattern. The warm Pacific SST last year almost pushed 2014 to a new record average surface temperature, and fossil fuel activists are pinning their Paris hopes on this year.

So it is timely for the Meteorologist who named this event to provide a clear explanation of the natural causes of the Blob phenomenon.

From Nicholas Bond (excerpted from post linked below):

Blob 101
The development of the blob of unusually warm water can be attributed largely to an unusual weather pattern that set up shop over a large region extending from the North Pacific Ocean across North America from October 2013 into February 2014.

This pattern featured a strong and long-lasting weather pattern with higher-than-normal pressure – called a ridge – over the ocean centered offshore of the Pacific Northwest. This ridge of high pressure reduced the number and intensity of storms making landfall, leading to reduced precipitation west of the Continental Divide compared to seasonal norms.

In a study published earlier this month, my colleagues and I fingered the stubborn high-pressure ridge mentioned above, and in particular the weak winds associated with it. The result was a lower-than-normal rate in how quickly heat is transferred from the ocean to the atmosphere, and slower movement of cooler water into the formation region of the blob.
In other words, the unusual atmospheric conditions produced less cooling than typical for the season from fall 2013 through much of the following winter, yielding the sea surface temperature anomaly pattern. So we can essentially blame the ridge for the blob, but what caused the ridge in the first place?

The ocean circulation – that is, the currents – and the weather during the past year, which was unusual in its own right, combined to cause the blob to evolve into a wide strip of relatively warm water along the entire West Coast of North America (see image, below).

This happens to be a pattern that has occurred before in association with decades-long shifts in ocean temperature known as the Pacific Decadal Oscillation (PDO). Previous expressions of the PDO have had major and wide-ranging impacts on the marine ecosystem including salmon and other species of fish; recent developments are receiving a great deal of attention from fishery-oceanographers along the West Coast.

http://theconversation.com/what-is-the-warm-blob-in-the-pacific-and-what-can-it-tell-us-about-our-future-climate-40140

Spitsbergen Triangle: Ground Zero for Climate Mysteries

Credit to Dr. Bernaerts for his writings on this subject, excerpts of which appear below.

The Island Nexus for Ocean Currents

From the Dutch: spits – pointed, bergen – mountains

The largest and only permanently populated island of the Svalbard archipelago in northern Norway. Constituting the westernmost bulk of the archipelago, it borders the Arctic Ocean, the Norwegian Sea, and the Greenland Sea. Spitsbergen covers an area of 39,044 km2 (15,075 sq mi), making it the largest island in Norway and the 36th-largest in the world.

The fact is that the winter temperatures made a jump of more than eight degrees Celsius at the gate of the Arctic Basin, after 1918. Nowadays, one century later, the event is still regarded as “one of the most puzzling climate anomalies of the 20th century”.

Dr. Bernaerts:

The overriding aspect of the location is the sea; the sea around Spitsbergen, the sea between particularly the Norwegian, the Greenland, and the Barents Seas (Nordic Sea). The Norwegian Sea is a huge, 3000 metres deep basin. This huge water mass stores a great amount of energy, which can transfer warmth into the atmosphere for a long time. In contrast the Barents Sea, in the southeast of Spitsbergen has an average depth of just around 230 metres. In- and outflow are so high that the whole water body is completely renewed in less than 5 years. However, both sea areas are strongly influenced by the water masses coming from the South. The most important element is a separate branch of the North Atlantic Gulf Current, which brings very warm and very salty water into the Norwegian Sea and into the Spitsbergen region. Water temperature and degree of saltiness play a decisive role in the internal dynamics of the sea body. And what might be the role of the huge basin of the Arctic Ocean, 3000 meters depth and a size of about 15 million square kilometers?

The difference towards the other seas mentioned is tremendous. The Arctic Ocean used to be widely ice covered in the first half of the 20th Century, the other seas only partly on a seasonal basis. Only between the open sea and the atmosphere an intensive heat transfer is permanently taking place. Compact sea ice reduces this transfer about 90% and more, broken or floating ice may change the proportion marginally. In this respect an ice covered Arctic Ocean has not an oceanic but ‘continental’ impact on the climate.

The Arctic Ocean is permanently supplied with new water from the Gulf Current, which enters the sea close at the surface near Spitsbergen. This current is called the West Spitsbergen current. The arriving water is relatively warm (6 to 8°C) and salty (35.1 to 35.3%) and has a mean speed of ca. 30 cm/sec-1. The warm Atlantic water represents almost 90% of all water masses the Arctic receives. The other ~10% comes via the Bering Strait or rivers. Due to the fact that the warm Atlantic water reaches usually the edge of the Arctic Ocean at Spitsbergen in open water, the cooling process starts well before entering the Polar Sea.

A further highly significant climate aspect of global dimension is the water masses the Arctic releases back to oceans. Actually, the outflow occurs mainly via the Fram Strait between Northeast Greenland and Spitsbergen, and together with very cold water from the Norwegian Sea basin the deep water spreads below the permanent thermocline into the three oceans.

http://www.arctic-heats-up.com/pdf/chapter_2.pdf

The Spitsbergen Event 1918-1919

Beginning around 1850 the Little Ice Age ended and the climate began warming. Before that, at least since 1650 marked the first climatic minimum after a Medieval warm period, the Little Ice Age brought bitterly cold winters to many parts of the world, most thoroughly documented in the Northern Hemisphere in Europe and North America. The decreased solar activity and the increased volcanic activity are considered as causes. However, the temperature increase was remote and once again effected by the last major volcanic eruption of the Krakatoa in 1883. Up to the 1910s the warming of the world was modest.

Suddenly that changed. In the Arctic the temperatures literally exploded in winter 1918/19. The extraordinary event lasted from 1918 to 1939 is clearly demonstrated in the graph showing the ‘Arctic Annual Mean Temperature Anomalies 1880 – 2004’. But this extraordinary event has a number of facets, which could have been researched and explained. Meanwhile almost a full century has passed, and what do we know about this event today? Very little!

Studies considering the causation of the warming offer sketchy rather than well founded ideas. Here are a few examples:
• Natural variability is the most likely cause (Bengtsson, 2004);
• We theorize that the Arctic warming in the 1920s/1930s was due to natural fluctuations internal to the climate system (Johannessen, 2004).
• The low Arctic temperatures before 1920 had been caused by volcanic aerosol loading and solar radiation, but since 1920 increasing greenhouse gas concentration dominated the temperatures (Overpeck, 1997).
• The earlier warming shows large region-to-region, month-to-month, and year-to-year variability, which suggests that these composite temperature anomalies are due primarily to natural variability in weather systems (Overland, 2004).
• A combination of a global warming signal and fortuitous phasing of intrinsic climate patterns (Overland, 2008).

Arctic Regime Change

These explanations (and others such as CO2 or the AMOC) do not come to grips with how extreme and abrupt was this event. In the Spring of 1917, sea ice reached all the way to Spitsbergen, the only time in a century.

And the next year, temperatures rocketed upward, as shown by the weather station there:

A look at the SST history shows clearly an event as dramatic as a super El Nino causing a regime change. But this is the Atlantic, not the Pacific. Cooling followed, but temperatures stayed at a higher level than before.

Summary

The warming at Spitsbergen is one of the most outstanding climatic events since the volcanic eruption of Krakatoa, in 1883. The dramatic warming at Spitsbergen may hold key aspects for understanding how climate ticks. The following elaboration intends to approach the matter from different angles, but on a straight line of thoughts, namely:

  • WHERE: the warming was caused and sustained by the northern part of the Nordic Sea in the sea area of West Spitsbergen the pass way of the Spitsbergen Current.
  • WHEN: The date of the commencement of warming can be established with high precision of few months, and which was definitely in place by January 1919.
  • WHY: the sudden and significant temperature deviation around the winter of 1918/19 was with considerable probability caused, at least partly, by a devastating naval war which took place around  the British Isles, between 1914 and 1918.

There is much more evidence and analysis supporting Dr. Bernaerts’ conclusions here:

http://climate-ocean.com/arctic-book/index.html


Conclusion:  Unless your theory of climate change can make sense of the Spitsbergen Event, then it cannot inspire confidence. You may not be entirely convinced by Dr. Bernaerts’ explanation, but he at least has one–nobody else  has even tried.